No. Individuals can only make one application per financial year, to a maximum of $10,000 across all super funds. If they apply for $10,000 against an account that has only $8,500 – they will only receive the $8,500.
However, if they have multiple accounts with less than $10,000 in any one account, they are able to nominate more than one account from which amounts are to be released when they apply to the ATO
For example, if they had two super accounts with $5,000 in each, they will be able to claim $5,000 from each fund at the time they make the application.